摘要 : Bidirectional electron transfer is about that exoelectrogens produce bioelectricity via extracellular electron transfer at anode and drive cytoplasmic biochemical reactions via extracellular electron uptake at cathode. The key factor to determine above bioelectrochemical performances is the electron transfer efficiency under biocompatible abiotic/biotic interface. Here, a graphene/polyaniline (GO/PANI) nanocomposite electrode specially interfacing exoelectrogens ( Shewanella loihica ) and augmenting bidirectional electron transfer was conducted by in-situ electrochemical modification on carbon paper (CP). Impressively, the GO/PANI@CP electrode tremendously improved the performance of exoelectrogens at anode for wastewater treatment and bioelectricity generation (about 54 folds increase of power density compared to blank CP electrode). The bacteria on electrode surface not only showed fast electron release but also exhibited high electricity density of extracellular electron uptake through the proposed direct electron transfer pathway. Thus, the cathode applications of microbial electrosynthesis and bio-denitrification were developed via GO/PANI@CP electrode, which assisted the close contact between microbial outer-membrane cytochromes and nanocomposite electrode for efficient nitrate removal (0.333 mM/h). Overall, nanocomposite modified electrode with biocompatible interfaces has great potential to enhance bioelectrochemical reactions with exoelectrogens.

摘要 : In their study of the truncation of Euler's pentagonal number theorem, Andrews and Merca introduced a partition function M k ( n ) to count the number of partitions of n in which k is the least integer that is not a part and there are more parts exceeding k than there are below k . In recent years, two conjectures concerning M k ( n ) on truncated theta series were posed by Andrews, Merca, and Yee. In this paper, we prove that the two conjectures are true for sufficiently large n whenever k is fixed.

摘要 : Real industrial scenarios struggle with the issues of a limited number of labeled samples and difficulty in accessing, which results in deep learning-based fault diagnosis models having poor generalization capabilities and decreased diagnostic accuracy. To address this problem, a semi-supervised prototype enhancement network (SSPENet) is proposed for rolling bearing fault diagnosis in this study. Firstly, a dual pooling attention residual network is proposed to be used in the feature extraction module. The goal is to efficiently extract the hidden features within rolling bearings, thus enabling the accurate classification of different sample categories. Subsequently, the Hungarian algorithm is utilized to design a strategic approach to update prototypes with pseudo-labels, which achieves the effect of augmenting prototypes by accurately adjusting the prototype position of each class of limited labeled samples through unlabeled samples, to improve the discriminative ability of the network model for fault classes. Finally, validation and experimental analysis are carried out on two bearing datasets, which achieve the average diagnostic accuracy of the proposed model to be above 90 % for both 1-shot and 2-shot cases, obtaining more satisfactory diagnostic results.

摘要 : Using linear-stability analysis, two-dimensional modulation instability (MI) of plane wave is studied in nonlocal media with competing cubic–quintic (CQ) nonlinearities, which shows that MI can be effectively eliminated by strong nonlocality and competing quintic nonlinearity. Furthermore, propagation properties of higher-order soliton clusters, i.e., Hermite–Gaussian (HG) and Laguerre–Gaussian (LG) solitons are also investigated. Bifurcated solutions of these solitons are obtained analytically with variational approach. We also demonstrate in detail the propagation dynamics of the HG and LG solitons with split-step Fourier transform.

摘要 : Engineering binary transitional metal sulfides (BTMSs)-based electrode materials with a rationally designed constituent architecture is a viable strategy for improving their rate capability and electrochemical durability, which provides a possibility for their application in supercapacitors (SCs). Herein, a novel three-dimensional (3D) flower bud-like phosphorus and tungsten co-doped NiCo 2 S 4 and MoS 2 composites (P, W-NCS@MS) is prepared on conductive carbon cloth using the hydrothermal method. The effects of P, W-doping, or MoS 2 -combination on the morphology, structure and electrochemical properties of NiCo 2 S 4 -based electrode materials are systematically studied. The designed P, W-NCS@MS achieves a high specific capacity of 1250C g −1 at 1 A g −1 and a satisfactory capacity retention of 80 % after 10, 000 cycles. In addition, the asymmetric supercapacitor (ASC) constructed through P, W-NCS@MS and activated carbon electrodes delivers a high energy density of 65.0 Wh kg −1 at the power density of 400 W kg −1 and shows satisfactory cycling stability of 85 % capacitance retention after 20, 000 cycles. Notably, the assembled ASC device successfully powered electronic devices in a serial circuit, highlighting its prospective applications in energy storage. This work offers a viable design approach for heteroatom doping and hierarchical interface structures in composite electrode materials toward high-performance SCs.

摘要 : Pyrethroids are widely used insecticides worldwide, while their on-site and rapid detection still faces technological challenges. Herein, an innovative detection mechanism was designed for deltamethrin, a typical kind of type II pyrethroids, based on a dual-emitting fluoroprobe consisting of NH 2 -SiQDs and Eu 3+ . Deltamethrin can rapidly hydrolyze into 3-phenoxybenzaldehyde (3-PBD) and react specifically with fluoroprobe, causing fluorescence quenching of SiQDs while maintaining the fluorescent stability of Eu 3+ . Building upon the above fluorescence-responsive principle, SiQDs@Eu 3+ provided satisfactorily dual-emitting signals, realizing the highly-selective and sensitive detection of deltamethrin. Correlation between the surface structure of SiQDs and their absorption spectra was in-depth unraveled by TD-DFT calculation and FT-IR analysis. As for the analytical performance, the recovery and LOD of deltamethrin in lettuce, provided by SiQDs@Eu 3+, were comparable or even superior over conventional chromatographic analysis. Meanwhile, an innovative smartphone-based optical device was developed, which greatly decreased errors caused by the previously reported smartphone-based fluorescence detection.

摘要 : The main challenges (sluggish electron transfer, low energy density) hinder the future application of enzymatic biofuel cells (EBFCs), which urgent to take effective measures to solve these issues. In this work, a composite of Au nanoparticles decorated graphdiyne (AuNPs@GDY) is fabricated and employed as the carrier of enzyme (G6PDH), and a mechanism based on π-π interaction of electron transfer is proposed to understand bioelectrocatalysis processes. The results show that the AuNPs@GDY composite exhibits the highest current density among the three materials (GDY, AuNPs, and AuNPs@GDY), which is 3.4 times higher than that of GDY and 2.5 times higher than that of AuNPs. Furthermore, the results reveal that the AuNPs could increase the loading of enzymes and provide more active site for reaction, while GDY provides highly π-conjugated structure and unique sp/sp 2 -hybridized linkages interface. This work provides new insights to explore a theoretical basis for the development of more efficient bioelectrocatalytic systems.

摘要 : Bi 2 S 3 is regarded as one of the most promising thermoelectric materials because of its abundance, cost-effectiveness and environmentally friendly characteristics. This work delves into the impact of interstitial Cu on the composition, microstructure, and thermoelectric properties of the Cl-doped Bi 2 S 3 bulks. The introduction of interstitial Cu as donors generates free electrons without compromising electron mobility. The excessive Cu induces the precipitation of Cu/Bi-rich phase and the Cu ions dynamically diffuse from these precipitates into the Bi 2 S 3 lattice with increasing temperature. This effect significantly enhances electrical conductivity and power factor across a broad temperature range. Intriguingly, dense nanodomains are successfully constructed in the Bi 2 S 3 sample. This unique defect, coupled with interstitial Cu, nanodomains, precipitates, and dislocations, establishes the hierarchical structures, leading to a low lattice thermal conductivity of 0.34 W m −1 K −1 . Notably, the sample incorporating 4 at% Cu achieves an exceptional peak ZT value of 0.67 at 673 K.

摘要 : Nickel-iron based (Ni-Fe) catalysts are widely used in the electrolysis of water due to their high activity and low cost. However, the development of highly active non-precious metal catalysts is still a great challenge. Herein, self-supported nickel–iron phosphide is fabricated through a sulfurization/phosphorization approach (Ni-Fe-P-S-1/Ni-Fe-P-S-2). The prepared catalysts show excellent catalytic performance and stability. The HER performance of Ni-Fe-P-S-1 reaches 500 mA cm −2 with small overpotentials of 289 mV in alkaline freshwater. Meanwhile, the Ni-Fe-P-S-2 requires 312 and 375 mV to reach 500 mA cm −2 in alkaline freshwater and alkaline seawater for OER. Remarkably, at the current density of 500 mA cm −2, the Ni-Fe-P-S-1||Ni-Fe-P-S-2 electrolyzer requires only 1.85 V in alkaline. Interestingly, sustainable energies can power the electrolyzer effectively. The work provides methods for potentially promising and cost-effective electrocatalysts.

摘要 : Microbial polysaccharides (MPs) are biopolymers secreted by microorganisms such as bacteria and fungi during their metabolic processes. Compared to polysaccharides derived from plants and animals, MPs have advantages such as wide sources, high production efficiency, and less susceptibility to natural environmental influences. The most attractive feature of MPs lies in their diverse biological activities, such as antioxidative, anti-tumor, antibacterial, and immunomodulatory activities, which have demonstrated immense potential for applications in functional foods, cosmetics, and biomedicine. These bioactivities are precisely regulated by their sophisticated molecular structure. However, the mechanisms underlying this precise regulation are not yet fully understood and continue to evolve. This article presents a comprehensive review of the most representative species of MPs, including their fermentation and purification processes and their biomedical applications in recent years. In particular, this work presents an in-depth analysis into the structure-activity relationships of MPs across multiple molecular levels. Additionally, this review discusses the challenges and prospects of investigating the structure-activity relationships, providing valuable insights into the broad and high-value utilization of MPs.